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Ossila材料MEH-PPV CAS:138184-36-8 Ossila總代理
Ossila材料MEH-PPV CAS:138184-36-8 Ossila總代理
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供應(yīng)數(shù)量：
 2675
發(fā)布日期：
 2024/9/13
有效日期：
 2025/3/13
原 產(chǎn) 地：
 英國
已獲點擊：
 2675
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只用于動物實驗研究等

General Information

CAS number138184-36-8
Chemical formula(C18H28O2)n
Molecular weightMw = 372,942, Mn = 72,485 (PDI = 5.15)
Absorptionλmax 493 nm (toluene)
Fluorescenceλem 554 nm (toluene)
HOMO/LUMOHOMO = 5.3 eV, LUMO = 3.0 eV
Full namePoly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene]
SolubilityToluene or chlorobenzene
Classification / FamilyPPV derivatives, Hole-injection layer materials, Hole transport layer materials; Polymer light-emitting diodes (OLEDs), Organic photovoltaics (OPVs), Organic electronics

 

Product Details

Purity >99%
Thermogravimetric Analysis (TGA)371 °C (5% weight loss)
ColourRed fibers

Chemical Structure

chemical structure of MEH-PPV
Chemical Structure of MEH-PPV, Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene]; CAS No. 138184-36-8; Chemical Formula (C18H28O2)n.

Applications

Poly[2-methoxy-5-(2’-ethylhexyloxy)-1,4- phenylene vinylene] (MEH-PPV) is a PPV derivative that is particularly favourable for device fabrication due to its great solubility in most of the common organic solvents owing to its asymmetric side chains. To date, MEH-PPV is possibly one of the most celebrated and studied polymer semiconductors, recognising its applications in OPV, OFETs, polymer light-emitting diodes (PLED) and perovskite solar cells.

The first example of a polymer solar cell with a convincing understanding of the physics and chemistry involved was the bilayer heterojunction cell utilising the soluble polymer MEH-PPV and the Buckminsterfullerene C60 where a power conversion efficiency of 0.04% was obtained using monochromatic light.[1, 2]

Device structureITO/Al/PFNBrBTDZ05*/MEH-PPV/Au [3]                                                  
ColourOrange-Red orange-red
Max. EQE 2.71%
Max. Current Efficiency1.6 cd/A
Device structureITO/PEDOT:PSS/PPF-3,7SO10* (100 wt%):P-PPV (0.8 wt%): MEH–PPV (0.5 wt%)/Ba/Al [4]                    
ColourWhite white
Max. EQE6.9%
Max. Current Efficiency14.0 cd/A
Max. Power Efficiency7.6 lm W−1
Device structureITO/CFx/MEH-PPV/Ca/Al, ca [5]
ColourOrange-Red orange-red
Max. Luminance24,000 cd/m2
Max. Current Efficiency5.1 cd/A
Device structureITO /PEDOT:PSS/PFO:0.25 wt% MEH-PPV/Cs2CO3/Al [6]
ColourWhite white
Max. EQE            6%
Max. Current Efficiency11.2 cd/A
Max. Power Efficiency16 lm W−1
Device structureITO/PEDOT/PVK:polyTPD (1:1 wt%) 50 nm/PFO:MEH-PPV*(95.5:0.5 wt%) 70 nm/Ca/Al [7]                 
ColourWhite white
Max. Luminance~ 5,000 cd/m2
Max. Current Efficiency3.15 cd/A
Device structureITO/PEDOT (30 nm)/ poly-TPD(40 nm)/ DNA-CTMA*(20 nm)/ PFO:MEH-PPV (70 nm)/Cs2CO3(1 – 2 nm)/Al [8]
ColourWhite white
Max. Luminance10,500 cd/m2
Max. Current Efficiency10 cd/A
Device structureITO/MEH-PPV/TPBI doped by 10 wt % Cs2CO3/Cs2CO3/Ca/Al [9]
ColourOrange-Red orange-red
Max. EQE2.2%
Max. Luminance62,000 cd/m2
Max. Current Efficiency5.7 cd/A

*For chemical structure informations please refer to the cited references.

Characterisation (HPLC)

MEH-PPV, Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene], 138184-36-8

HPLC trace of MEH-PPV, Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene].

 

Literature and Reviews

  1. Photoinduced electron-transfer from a conducting polymer to buckminsterfullerene, N. Sariciftci et al., Science, 258, 1474–1476 (1992).
  2. Semiconducting polymer—buckminsterfullerene heterojunctions—diodes, photodiodes and photovoltaic cells, N. Sariciftci et al., Appl. Phys. Lett., 62, 585–587 (1993).
  3. High-efficiency inverted top-emitting polymer light-emitting diodes, L. Hou et al., Appl. Phys. Lett., 87, 153509 (2005); doi: 10.1063/1.2099528 .
  4. High-efficiency and good color quality white light-emitting devices based on polymer blend, J. Zou et al., Org. Electronics, 10, 843–848 ((2009), doi:10.1016/j.orgel.2009.04.007.
  5. High-efficiency polymer light-emitting diodes based on poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylene vinylene] with plasma-polymerized CHF3-modified indium tin oxide as an anode, C-C. Hsiao et al., Appl. Phys. Lett. 88, 033512 (2006); http://dx.doi.org/10.1063/1.2165192.
  6. Achieving High-Efficiency Polymer White-Light-Emitting Devices, J. Huang et al., Adv. Mater., 18, 114–117 (2006); DOI: 10.1002/adma.20050110.
  7. Enhanced performance of white polymer light-emitting diodes using polymer blends as hole-transporting layers, Q. Sun et al., Appl. Phys. Lett. 89, 153501 (2006); http://dx.doi.org/10.1063/1.2360248.
  8. Multilayer white polymer light-emitting diodes with deoxyribonucleic acid-cetyltrimetylammonium complex as a hole-transporting/electronblocking, Q.Sun et al., Appl. Phys. Lett. 92, 251108 (2008); doi: 10.1063/1.2948864 .
  9. Design of hole blocking layer with electron transport channels for high performance polymer light-emitting diode, C-C. Hsiao et al., Adv. Mater., 20, 1982–1988 (2008); DOI:10.1002/adma.200702150.
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